N 58° 40‘ 2.87“ – E 9° 11‘ 35.087“

Using ammonia for hydrogen
transportation and provision

Ensuring the safe, effective, and economical storage of hydrogen for road transport is a crucial technological challenge in the pursuit of a low-carbon economy. Ammonia, in its liquefied form, contains 50% more hydrogen by volume than liquid hydrogen, making it an appealing option for hydrogen fuel cell vehicles due to its high hydrogen content of 17.8wt% and ease of storage and transportation. Ammonia can be readily decomposed or „cracked“ into nitrogen and hydrogen gases, with optimal catalytic decomposition being critical to achieve. Iron is an inexpensive material that can achieve the ideal decomposition at high temperatures above 700°C. However, lower-temperature decomposition methods currently require rare-metal catalysts like ruthenium, which increases energy costs. Cost reductions and the optimization of catalyst and reaction processes are necessary to minimize energy losses from the ammonia decomposition reaction to about 7% of the stored energy of ammonia, which is the theoretical minimum value.


Liquid ammonia has 50% more hydrogen by volume than liquid hydrogen.

Reducing carbon emissions in the global shipping industry

The International Maritime Organisation (IMO) has set a target of reducing greenhouse gas (GHG) emissions from international shipping by at least 50% (compared to 2008) by 2050. One of the major hurdles in achieving this target is the long lifespan of large ships, which is around 25 years. The maritime industry is looking at ammonia as a green fuel for shipping due to its potential for retrofitting, ease of storage, existing maritime networks and bunkering capabilities, flexible use in both combustion engines and fuel cells, and relative decarbonisation potential [10]. The Environmental Defense Fund (EDF) has recently published a report on the potential of ammonia in decarbonising the international maritime sector, highlighting Morocco as a potential key player with large commercial ports close to key shipping routes and an abundance of renewable energy resources [11]. MAN Energy Solutions is leading the way in decarbonising the maritime economy by developing ammonia-fuelled engines based on current liquid natural gas technology, with the first ammonia engine expected to be in operation by early 2022 [12]. Lloyd’s Register has also granted Approval in Principle for ammonia-fuelled vessels and is working on concept designs for bulk carriers and ultra-large containerships. ABS, MAN-ES and SDARI are collaborating to develop ammonia-fuelled feeder vessels [13,14,15].

According to research, global ammonia production annually emits approximately 1.8% of overall global carbon dioxide emissions, equating to 176 million tonnes of ammonia per year. To achieve net-zero targets, it is essential to create and implement an urgent plan for decarbonizing ammonia production, which would create opportunities to replace fossil fuels with ammonia in other applications.

The majority of the carbon dioxide released during ammonia production comes from the steam methane reforming (SMR) process used to produce hydrogen. To manage the transition to net-zero carbon systems, blue hydrogen can be produced in the short term by combining carbon capture and storage with the SMR process. However, this is not a viable long-term solution in a zero-carbon economy. Electrolyzing water to produce green hydrogen presents a pathway to zero-carbon ammonia production. However, it depends on low-cost sustainable electricity and a continued decrease in electrolyzer costs. Currently, renewable energy electricity costs are close to a tipping point for the affordable production of zero-carbon green ammonia in regions rich in wind and solar energy. A green ammonia market would significantly enhance economic opportunities to extend renewable penetration into the energy economy. Nonetheless, given the poor overall efficiency, the energy system must be considered to ensure that ammonia production is relevant to the local situation.

Further research could lead to the development of various processes to produce green ammonia, such as new production catalysts, electrochemical ammonia production, and chemical looping processes. Some of these technologies may address the challenge of directly coupling ammonia production to intermittent renewable power. Ammonia is a convenient energy storage medium that can be stored in large quantities as a liquid at modest pressures (10-15 bar) or refrigerated to -33°C, with an energy density of approximately 40% of petroleum.

As a zero-carbon fuel, ammonia can be utilized in fuel cells or through combustion in internal combustion engines, industrial burners, and gas turbines. The maritime industry is likely to adopt ammonia as a fuel early on, and it has the potential to decarbonize heavy road transport, rail, and aviation.

Ammonia can also be utilized to generate electricity via fuel cells, gas turbines, or internal combustion engines, which can then provide power to the grid or remote areas. Furthermore, as an efficient energy carrier, it has the potential to be a key player in nascent international sustainable energy supply chains. It is more affordable and easier to transport and store than pure hydrogen, has existing international infrastructure, can be cracked to produce hydrogen when needed, and is itself a zero-carbon fuel. Ammonia also has potential use in district heating systems. Despite the established global manufacturing and distribution system and the safe transportation and use of ammonia, new applications will require a careful risk assessment, and additional control measures may be necessary to reduce risks to health and the environment.

[10] Gong W, Willi ML. 2008 United States Patent Application Publication – Caterpillar Inc. See https://patentimages.storage.googleapis.com/b4/b0/74/315157b86c9292/US20100019506A1.pdf

(accessed 14 November 2019).

[11] Ash N, Scarbrough T. 2019 Sailing on Solar: Could green ammonia decarbonise international shipping? Environmental Defense Fund.

See https://europe.edf.org/file/399/download?token=agUEbKeQ (accessed 23 May 2019).

[12] MAN Energy Solutions. 2019 Engineering the future two-stroke green-ammonia engine. See https://marine.man-es.com/docs/librariesprovider6/test/

engineering-the-future-two-stroke-green-ammonia-engine.pdf?sfvrsn=7f4dca2_4 (accessed 14 November 2019).

[13] Shanghai Merchant Ship Design & Research Institute. 2019 Linkedin https://www.linkedin.com/posts/shanghai-merchant-ship-design-%26-researchinstitute_

180k-dwt-bc-of-carbon-free-issued-and-obtained-activity-6609776461731717120-oZtk/ (accessed 20th December 2019).

[14] Lloyd’s Register. 2019 Industry project to design ammonia-fuelled 23k ULCS concept. See https://www.lr.org/en/latest-news/aip-ammonia-fuelled-ulcs/

(accessed 20 December 2019).

[15] American Bureau of Shipping (ABS). 2019 ABS, MAN & SDARI join forces to develop ammonia-fuelled feeder vessel. See https://ww2.eagle.org/en/

news/press-room/abs-man-sdari-develop-ammonia-fueled-feeder-vessel.html (accessed 20 December 2019).